HYDROGEN EMBRITTLEMENT TEST
Contents
Amid the global push toward a decarbonized society, hydrogen is emerging as a next-generation energy source. ‘Green hydrogen’, which emits no CO2 when combusted, is expected to be a key solution for reducing greenhouse gas emissions.
Hydrogen’s potential extends beyond climate change mitigation; it also enhances energy security. Developing domestic hydrogen production and utilization capabilities reduces dependence on fossil fuel imports and mitigates geopolitical risks. Hydrogen also functions as an ‘energy carrier’, absorbing fluctuations in renewable energy output and supporting a stable electricity supply. Furthermore, efforts are underway to produce hydrogen using the stable output of nuclear power. By combining diverse power sources, we can establish a stable hydrogen supply system.
Hydrogen is also set to transform the industrial sector. In particular, the steel industry is shifting to steelmaking processes that use hydrogen as a reducing agent, significantly contributing to the reduction of CO2 emissions. In the power sector, combustion technologies such as hydrogen gas turbines and hydrogen engines are being developed, enabling the use of existing facilities while reducing CO2 emissions.
To achieve widespread hydrogen adoption, advancements in transportation and storage technologies are essential. Because hydrogen has a low volumetric energy density at ambient temperature and pressure, its liquefaction—by cooling it to approximately 20 K (−253°C), which reduces its volume to about 1/800—is being explored as a means of efficient large-scale transportation. This enables large-scale, long-distance transport. In addition, efforts are underway to repurpose existing gas pipeline networks into hydrogen-dedicated pipelines, with the aim of establishing broad and stable hydrogen supply networks.
Nevertheless, significant challenges remain before the realization of a hydrogen-based society. Hydrogen can cause brittleness in some metallic materials, making it necessary to ensure the safety and durability of pipelines and storage tanks. Significant hurdles also remain in the form of high energy costs for liquefaction and compression, the development of related technologies, and the establishment of legal and regulatory frameworks.
At Kobe Material Testing Laboratory Co., Ltd., we believe hydrogen holds the potential to drive technological innovation and foster new industries across every stage—production, storage, transport, and use. We are actively engaged in developing advanced testing and evaluation technologies for materials in hydrogen environments. The following sections provide a basic overview of hydrogen embrittlement mechanisms along with our testing achievements and plans for technological development.
The demand for using structural materials in hydrogen environments is increasing, but challenges remain.
One of the major concerns in strength design is hydrogen embrittlement — a phenomenon where hydrogen atoms penetrate and diffuse into metallic materials, potentially degrading their mechanical properties in various ways.
To promote the use of hydrogen energy, challenges exist not only in evaluating material safety but also in conducting the tests themselves.
Challenges
Advantages:
➡ allowing us to meet diverse testing needs at reasonable cost.
Hydrogen Material Test Conditions and Scope at KMTL
Analysis of Fractured Hollow Specimens Using Electron Backscatter Diffraction (EBSD)
Using scanning electron microscopy (SEM) to observe the fracture surface of tested hollow specimens revealed multiple secondary cracks in addition to the primary crack. This suggests that hydrogen embrittlement promotes localized crack initiation, leading to failure through multiple damage pathways.
Applying Electron Backscatter Diffraction (EBSD) provides detailed information on the microstructure near the fracture area. The resulting orientation maps are essential for understanding the mechanisms of hydrogen embrittlement.
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Electrolytic hydrogen charging is a method used to add hydrogen to metallic materials. The specimen is polarized in an aqueous solution, allowing hydrogen to permeate the material’s surface and diffuse into its interior. It has been primarily used to study hydrogen embrittlement and delayed fracture of steels under corrosive environments. Hydrogen embrittlement tends to increase with the hydrogen concentration in the steel. Electrolytic hydrogen charging allows us to simulate hydrogen effects in actual environments to evaluate the hydrogen resistance of steel.
At Kobe Material Testing Laboratory Co., Ltd., we faced the challenge of hydrogen desorption during tensile tests in the atmosphere conducted after hydrogen charging. The following section introduces our developed method for maintaining hydrogen charging during tensile tests, effectively solving this issue.
Stress-Stroke Curves
Thermal Desorption Analysis (TDA) of Hydrogen
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High pressure hydrogen gas vessels and piping are essential for hydrogen-energy related products and infrastructure, including FCV fuel tanks, hydrogen station refueling equipment, and large-scale hydrogen transportation and storage facilities. While these components enhance energy density and efficiency, they require specialized technologies and materials to handle the pressure safety. Strict safety standards and regulations necessitate extensive material testing in a high-pressure hydrogen gas environment. At Kobe Material Testing Laboratory Co., Ltd., we have established testing capabilities for SSRT, fatigue life, and fatigue crack growth tests under high pressure hydrogen gas environments. This was achieved by integrating a specially designed compact pressure vessel into a general-purpose hydraulic servo-type fatigue testing system.
System for SSRT and fatigue life tests
System for fatigue crack growth and fracture toughness tests
Our dedicated explosion-proof test room has been registered as a High-Pressure Gas Production Facility in Hyogo Prefecture. Tests are conducted in full compliance with safety regulation by Japanese law, including gas detectors, forced exhaust fans, explosion-proof fluorescent lights, and regular voluntary inspections.
SSRT test result
Fatigue crack growth test result
Fatigue life test result
SSRT test specimen
CT specimen for fatigue crack growth test
Fatigue life test specimen
CT specimen for fracture toughness test
In all industrial fields, there is a need to take samples from actual products or components and conduct various material tests while simulating similar environments. However, limitations on the dimensions of materials that can be taken from actual machines often result in specimens that do not meet the size recommended by general test standards. We specialize in miniature testing technology, where small samples taken from actual components are machined into specimens and subjected to a range of testing methods. This technology has been adapted for high-pressure hydrogen gas environment, resulting in our original test method described in this document. For further details, please scan the QR code to explore our miniature testing services.
Hydrogen atoms in metals diffuse significantly faster than other solute atoms such as carbon. Many researchers identify hydrogen diffusion as a primary cause of hydrogen embrittlement. Kobe Material Testing Laboratory Co., Ltd. has developed an experimental method for determining hydrogen diffusivity (D). Hydrogen concentration distribution analysis using FEM, based on this hydrogen diffusivity is shown as follows.
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Fitting analysis results
Diffusion simulation by FEM analysis
TEST SERVICE
KMTL provides a wide range of testing services including fatigue and creep testing to support safety and security for society at large.